The irreplaceable law of nutrient elements means that every essential nutrient element in plants has its special function and cannot be replaced by other elements. A plant is necessary for a certain nutrient element, because it has one or more special functions and is irreplaceable by other elements. However, this does not mean that there are no similarities between elements, or even no similarities. In fact, some elements have similar functions in plant metabolism, that is, they can all play similar roles in a certain metabolic process or a certain part of a metabolic process, so they can partially replace each other. A prominent example is the similarity between potassium and sodium in some nutritional functions. An important function of potassium is to regulate osmotic pressure in plants, and sodium also has this function. When potassium is insufficient, sodium can replace potassium to adjust osmotic pressure and let potassium perform other more important physiological functions. The principle of partial substitution of potassium and sodium has certain significance in growth. Some sodium-loving crops (such as sugar beet and barley) can be partially replaced by sodium, which not only saves the amount of potassium fertilizer but also does not cause crop yield reduction. However, it should be pointed out that the similarity or substitution between these elements is only partial and secondary, and most nutrient elements have their special functions in plants and cannot be completely replaced by other elements.